Design novel optical sensor for determination of bismuth based on immobilization of 4-(4-nitrophenyl)-1-naphthol on a triacetylcellulose membrane

Authors

Department of Chemistry, Faculty of Science, Islamic Azad University-Arak Branch, Arak, Iran

Abstract

A novel optical sensor has been proposed for sensitive determination of bismuth ion based
on immobilization of 4-(4-nitrophenylazo)-1-naphthol on a triacetylcellulose membrane.
Chemical binding of bismuth ions in solution with a 4-(4-nitrophenylazo)-1-naphthol
immobilized on the triacetylcelluse surface could be monitored spectrophotometrically. The
optode shows excellent response over wide concentration range 0.4-3.6 μg mL-1 bismuth with a
limit of detection of 0.14 μg mL-1 bismuth. The influence of factors responsible for the improved
sensitivity of the sensor were studied and identified. The response time of the optode was 30 sec
for a stirrer solution. The influence of potential interfering ions on the determination of 0.4 μg
mL-1 bismuth was studied. The proposed optode was applied to the determination of bismuth in
pharmaceutical formulation samples.

Keywords


[1] N. Alizadeh, A. Moemeni, M. Shamsipur, Anal. Chim. Acta 464 (2002) 187-196.
[2] H.Y. Luo, X.B. Zhang, J.H. Jiang, C.Y. Li, J. Peng, G.L. Shen, R.Q. Yu, Anal. Sci. 23 (2007) 551-
555.
[3] A.A. Ensafi, M. Bakhshi, Sens. Actuators B 96 (2003) 435-440.
[4] A. Safavi, M. Sadeghi, Anal. Chim. Acta 567 (2006) 184-188.
[5] I. Oehme, O.S. Wolfbeis, Microchim. Acta 126 (1997) 177-192.
A. Niazi & Sh. Karimi Afshar / J. Iran. Chem. Res. 4 (2011) 105-111
111
[6] M.M.F. Choi, K.O.P. Chung, X. Wu, Talanta 56 (2002) 1027-1038.
[7] S. Rasegarzadeh, Z. Moradpour, Anal. Lett. 40 (2007) 2993-3001.
[8] A. Safavi, A.R. Banazadeh, Food Chem. 105 (2007) 1106-1111.
[9] A. Safavi, M. Bagheri, Sens. Actuators B. 99 (2004) 608-612.
[10] T.J. Sands, T.J. Canrdwell, R.W. Cattral, J.R. Farrell, P.J. Iles, S.D. Kolev, Sens. Actuators B 85
(2002) 33-41.
[11] J.J. Lurie, Handbook of Analytical Chemistry, Mir Publication, Moscow, 1978.
[12] T.P. Jones, M.D. Porter, Anal. Chem. 60 (1988) 404-406.
[13] Y. Kostov, S. Teankov, Anal. Chim. Acta 280 (1993) 15-19.
[14] R. Narayanaswamy, S.H. Alabbas, D.C. Ashworth, B. Bezzaa, S.A. Momin, Sens. Actuators A 51
(1996) 129-134.